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Lithium Iron Phosphate Battery vs. Lead-Acid Battery: How to Choose?

When selecting batteries for vehicles, RVs, energy storage devices, and other equipment, many people are confused about “whether to choose lithium iron phosphate batteries or lead-acid batteries”. The two differ significantly in cost, performance, and applicable scenarios, and the choice is not simply a matter of “the expensive one is better” or “the cheap one is sufficient”. 

This article will compare them from four dimensions—core characteristics, performance parameters, cost-effectiveness, and applicable scenarios—to help you make the optimal choice based on your own needs. Complex concepts will be explained with specific examples to ensure easy understanding.

I. First, Understand: Core Characteristic Differences Between the Two Types of Batteries

To choose the right battery, you first need to understand its “fundamentals”—core composition and key characteristics, which form the basis for all subsequent comparisons.

(1) Lithium Iron Phosphate Battery (LiFePO₄): Representative of High Performance

Its positive electrode is lithium iron phosphate with an olivine structure, the negative electrode is graphite, the electrolyte is a lithium salt organic solvent, and a BMS (Battery Management System) board is required to prevent overcharging, over-discharging, or short circuits.

It has prominent core advantages:

  • High energy density: Reaching 120Wh/kg, which is 3-4 times that of lead-acid batteries. This means it is lighter for the same capacity. For example, an RV requiring a 200Ah battery may only need a 10kg lithium iron phosphate battery, while a lead-acid battery would weigh over 25kg.
  • Long cycle life: It can be cycled more than 2000 times (with capacity remaining over 80% after cycling). If cycled once a day, it can be used for more than 5 years.
  • Fast charging: Supporting 1.5C fast charging, it can be fully charged in 40 minutes, as efficient as fast charging for mobile phones.

However, it also has shortcomings:

  • High initial price: Usually about 3 times that of lead-acid batteries.
  • Restricted low-temperature charging: It is difficult to charge when the temperature is below 0°C, unless the battery itself retains heat after recent discharge or uses professional low-temperature battery cells.

(2) Lead-Acid Battery (Taking Sealed Lead-Acid Battery VRLA as an Example): Cost-Effective Veteran

Structurally, it adopts a valve-regulated design, divided into AGM (Absorbent Glass Mat) and gel electrolyte types, focusing on “maintenance-free” operation. Its core reaction is the reversible reaction of “Pb + PbO₂ + 2H₂SO₄ = 2PbSO₄ + 2H₂O“, and it reduces electrolyte loss through oxygen recombination technology.

Its biggest advantages are:

  • Low price: For example, a 48V20Ah lead-acid battery costs only about US$70, suitable for scenarios with limited budgets.
  • Flexible low-temperature charging: It can be charged with low current even at -20°C, making it more convenient for use in northern winters.
  • Mature technology and strong adaptability: It is commonly used in traditional fuel vehicles, low-end UPS backup power supplies, etc.

But its disadvantages are also obvious:

  • Low energy density: Only 30-40Wh/kg, which is more than 55% heavier than lithium iron phosphate batteries for the same capacity.
  • Short cycle life: Only 300-500 cycles. If cycled once a day, it may need to be replaced in about 1 year.
  • Restricted depth of discharge: Discharge cannot be lower than 50% (otherwise, plate sulfation will occur, shortening the service life). For example, to meet a usable capacity of 100Ah, a 200Ah lead-acid battery must be purchased.

II. Compare Performance: Key Parameters Determine "Usability"

When choosing a battery, “usability” depends on specific performance, such as charge-discharge efficiency, temperature adaptability, and installation flexibility—these parameters directly affect the user experience.

(1) Discharge Performance: Who Can "Provide Sustained Power"?

Lithium iron phosphate batteries have a major advantage: a flat discharge curve.

The voltage remains almost constant throughout the discharge cycle, and the output power is also stable. Just like a flashlight using a lithium iron phosphate battery, the light remains bright from full charge to depletion, and only goes out when the battery is completely dead. In contrast, lead-acid batteries exhibit the “flashlight effect”: the voltage is high and the light is bright in the early stage of discharge, but the voltage drops sharply in the later stage, the light dims gradually, and the battery “loses power” before being fully discharged.

In addition, the discharge rate has different effects on the two. The discharge rate is expressed by “C”, where C = discharge current / rated capacity. For example, discharging a 100Ah battery with a 100A current is 1C. When the discharge rate is greater than 0.1C (such as rapid power consumption by high-power equipment), the actual capacity of lead-acid batteries decreases significantly—at 0.8C discharge, the capacity is only 60% of the rated capacity. In contrast, the capacity of lithium iron phosphate batteries is hardly affected by the discharge rate: a 100Ah-rated capacity battery can still output nearly 100Ah of power at 0.8C discharge.

(2) Temperature Adaptability: Who Is More Reliable in Extreme Environments?

Temperature varies greatly in different scenarios, so the battery’s “durability” is crucial.

In high-temperature environments (such as outdoor areas at 55°C in summer), lithium iron phosphate batteries perform better—their cycle life is twice that of lead-acid batteries at room temperature, making them suitable for energy storage devices or RVs in hot southern regions. In contrast, lead-acid batteries are prone to accelerated aging at high temperatures, shortening their service life.

In low-temperature environments (such as -20°C in northern winters), the capacity of both decreases, but their performances differ: the discharge capacity of lithium iron phosphate batteries can maintain 70% of the rated capacity, higher than the 45% of lead-acid batteries. Therefore, when used in outdoor lighting or low-temperature equipment, lithium iron phosphate batteries have a longer “battery life”. However, lead-acid batteries can be charged at low temperatures, while lithium iron phosphate batteries are difficult to charge below 0°C—this is particularly important when charging car starter batteries in northern winters. (The low-temperature high-rate battery developed by Enov enables easy startup of cars in northern winters.)

(3) Installation and Storage: Who Is More "Worry-Free"?

In terms of installation, lithium iron phosphate batteries are more flexible. Since each cell is individually sealed without leakage, they can be installed horizontally, upside down, or vertically. For example, in RVs with limited internal space, they can be flexibly installed in corner positions. In contrast, lead-acid batteries cannot be installed upside down, as this may cause exhaust problems, limiting their installation positions.

In terms of storage, the requirements for the two are opposite: lithium iron phosphate batteries cannot be stored at 100% state of charge (SOC), as long-term storage at full charge will shorten their service life. Lead-acid batteries, however, have a high self-discharge rate (more than 5 times that of lithium iron phosphate batteries) and must be stored at 100% charge; otherwise, they are prone to power loss and damage. Many people use a trickle charger to keep lead-acid batteries charged during storage, which is rather troublesome.

III. Calculate Costs: Don’t Just Look at the Initial Price—Lifecycle Cost Is More Critical

Many people choose lead-acid batteries because they think they are “cheap”, but they overlook “long-term costs“. Taking a 10-year period as an example, we can calculate the lifecycle cost, and you will find a significant difference.

(1) Initial Cost: Lead-Acid Batteries Have an Advantage

Taking the common requirement of “meeting a usable capacity of 200Ah” as an example:

  • Lead-acid batteries: Since the depth of discharge cannot be lower than 50%, a 400Ah lead-acid battery pack is required, costing approximately 800 US dollars.
  • Lithium iron phosphate batteries: With a discharge depth of up to 100%, a 200Ah battery is sufficient, costing approximately 1600 US dollars.

In the initial stage, lead-acid batteries are indeed cheaper, costing only 1/2 to 1/3 of lithium iron phosphate batteries.

(2) Lifecycle Cost: Lithium Iron Phosphate Batteries Are More Economical

Lifecycle cost includes “replacement costs” and “maintenance costs“:

  • Lead-acid batteries: With a cycle life of 300-500 times, they need to be replaced every 3-5 years. Within 10 years, 2-3 replacements are required. Each replacement not only incurs battery costs (800 US dollars per time) but also labor installation fees and old battery disposal fees. The total 10-year cost is approximately 2400 US dollars. Moreover, lead-acid batteries require regular electrolyte checks to prevent sulfation, resulting in hidden maintenance costs in the long run.
  • Lithium iron phosphate batteries: With a cycle life of more than 2000 times, they do not need to be replaced within 10 years, and maintenance costs are almost zero (no need to check electrolytes or worry about sulfation). The total 10-year cost is the initial 1600 US dollars, which is 800 US dollars less than that of lead-acid batteries.

More importantly, lithium iron phosphate batteries can achieve the same performance with lower capacity. For example, to meet a usable capacity of 100Ah, a 300Ah lead-acid battery is needed (discharging 30% is safe), while a 100Ah lithium iron phosphate battery is sufficient. This further reduces the initial investment, making the lifecycle cost advantage of lithium iron phosphate batteries more prominent.

IV. Choose Based on Scenarios: Different Needs Correspond to Different Choices

There is no “absolutely good” battery, only “more suitable” ones. Combining your usage scenarios and core needs is the key to selecting the most appropriate battery.

(1) Scenarios Where Lithium Iron Phosphate Batteries Are Preferred

  • High-frequency cycling and long-life requirements: Such as the start-stop systems of taxis and hybrid vehicles (cycled multiple times a day) and RV energy storage (long-term use). Lithium iron phosphate batteries have a service life of more than 5 years, eliminating the need for frequent replacements and saving maintenance time.
  • Lightweight and space-constrained scenarios: Such as electric vehicles, electric motorcycles, and robots. Lithium iron phosphate batteries are lightweight (55% lighter than lead-acid batteries) and compact, reducing the load on equipment and enabling flexible installation in narrow spaces.
  • High-efficiency charging and low-maintenance requirements, Such as 5G base station backup power supplies and solar energy storage systems. Lithium iron phosphate batteries support 40-minute fast charging, enabling rapid power recovery after power outages. They also require no dedicated personnel for regular maintenance, making them suitable for unattended scenarios.
  • New energy vehicle auxiliary power supplies: They are compatible with BMS systems and can perfectly match the electronic control systems of new energy vehicles. They also improve the overall vehicle range (lightweight reduces energy consumption). For example, BYD hybrid models use lithium iron phosphate starter batteries, saving US$200 per vehicle in replacement costs during their lifecycle.

(2) Scenarios Where Lead-Acid Batteries Are Preferred

  • Budget-sensitive and short-term use scenarios: Such as starter power supplies for low-end fuel vehicles (only used for ignition, with few cycles) and temporary backup power supplies (used occasionally during power outages). Lead-acid batteries have low initial costs and high cost-effectiveness for short-term use.
  • Low-temperature charging and extreme environment scenarios: Such as fuel vehicles in northern winters (requiring low-temperature charging) and outdoor low-temperature equipment (used below -20°C). Lead-acid batteries can be charged at low temperatures, offering stronger adaptability. (Nowadays, low-temperature lithium iron phosphate batteries launched by ENOV can also be used in low-temperature environments.)
  • Scenarios compatible with existing lead-acid facilities, Such as old UPS systems and traditional industrial equipment. The circuit design of these devices is adapted to lead-acid batteries; replacing them with lithium iron phosphate batteries may require circuit modifications, resulting in higher costs. Thus, continuing to use lead-acid batteries is more practical.

V. Summary: A Sentence to Help You Decide

If your core needs are long-term use, low maintenance, and high performance (such as for RVs, new energy vehicles, and high-frequency energy storage), and you are willing to pay for the early technical premium, choose lithium iron phosphate batteries—they are more economical over a 10-year cycle.

If your needs are short-term use, tight budget, and low-temperature charging (such as for low-end fuel vehicles, temporary backup power supplies, and equipment used in northern winters), choose lead-acid batteries—they meet basic needs with low initial costs.

In the future, as the cost of lithium iron phosphate batteries decreases by 8%-10% annually (material costs are expected to drop by 24% in 2025), the price gap between them and lead-acid batteries will continue to narrow. Meanwhile, lead-acid batteries face environmental compliance pressures (high lead content causes pollution if not recycled properly), so lithium iron phosphate batteries will have a wider range of applications.

Finally, a reminder:

“Currently, both lead-acid batteries and lithium batteries are widely used in battery applications. With advancements in battery technology and growing environmental awareness, lithium batteries will play an increasingly significant role. This is precisely why ENOV continuously refines its lithium battery R&D and production techniques. If you have any thoughts on the battery industry, feel free to reach out anytime!”

—— Rayne

lITHIUM MOTORCYCLE STARTER BATTERY

Lithium motorcycle starter battery(all)

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